Sintering of ferrous metallic compacts: Chemical reactions that involve interstitial elements

Sintering and Foaming of Barium Silicate Glass Powder Compacts

The manufacture of sintered glasses and glass-ceramics, glass matrix composites, and glass-bounded ceramics or pastes is often affected by gas bubble formation. Against this background, we studied sintering and foaming of barium silicate glass powders used as SOFC sealants using different powder milling procedures. Sintering was measured by means of heating microscopy backed up by XPD, differen...

Lubricant Pyrolysis During Sintering of Powder Metallurgy Compacts

The chemistry surrounding the pyrolysis of N,NЈ-ethylenebisstearimide (EBS) compacted with iron powder is described for the first time. Heat treatment is carried out in a 5 vol pct hydrogen atmosphere (balance nitrogen) over the 100 °C to 850 °C range. The exhaust from the furnace is monitored by Fourier transform infrared and dispersive ultraviolet absorption spectroscopy; condensable material...

Conservation Equations for Chemical Elements in Fluids with Chemical Reactions

It is well known that when chemical reactions occur, the masses of the participating molecules are not conserved, whereas the masses of the nuclei of the chemical elements constituting these same molecules, are conserved. Within the context of non-equilibrium thermodynamics, the first fact is expressed by the differential balance equations, for the densities of the chemically reacting molecules...

Microstructural evolution of mullite during the sintering of kaolin powder compacts

Kaolin particles are usually ̄aky in shape. In the present study, kaolin powder compacts were prepared by applying the diepressing technique. The kaolin ̄akes tend to lie down on the plane which is perpendicular to the die-pressing direction. The powder compact thus shows anisotropic shrinkage after ®ring. A series of phase transformations take place as the kaolin is ®red at elevated temperatur...

A Study of Millimeter-Wave Sintering of Fine-Grained Alumina Compacts